No, in a word! You won’t know, after an hour or so, how much of the carb you’ve just eaten has been converted to blood glucose, because it’s difficult to gauge how fast (or slowly) it’s digesting, given the confounding factors of protein and fat in the pastry and sausage etc, so I think any guess at this stage would be useless.
The best thing, I think, would be to inject immediately after eating, having taken a mental note of what you’ve eaten, and do your best estimate of the carbs. You eat sandwiches often enough to be confident of your ability to work out the carbs in them, and you can look up sausage rolls.