With diabetes, we are susceptible to all carbohydrates, not just sugar as "complex carbs' are broken down to glucose.
Therefore, we tend to ignore the "of which are sugar" bits of the nutritional information.
Regarding how many carbs we should eat, like many things diabetes related, we are all different.
I have Type 1 which is different to type 2 but, as type 2 is more common, it is hard not to have seen the advice for type 2.
Amongst the forums the usual advice is to test your blood sugars before eating a meal and 2 hours later. If you blood sugars have risen more than 2 or 3 mmol/l in those 2 hours, it is a good indication that your body is struggling to handle that many carbs.
For this reason, a low carb (all carbs not just sugar) diet is common amongst people with type 2 diabetes. You will need to test to find out how many carbs your body can handle.
Getting back to your question about eating 23 slices of bread and assuming you ate nothing else with any sugar or carbs in it, the answer is "maybe but probably not". 690g of carbohydrates is a lot to eat in one day - a healthy pancreas would need to release a lot of insulin to manage that and the pancreas of someone with type 2 would need more.
But my key messages to you on this topic are
- you need to watch ALL carbohydrates
- we are all different. There is no one rule for all diabetics.